Styrene-Butadiene-Styrene Block Copolymer: An In-Depth Commentary

Historical Development

People have tinkered with polymers for over a century, but real momentum kicked in during the 1960s, when the push for better-performing rubber alternatives grew stronger. Traditional vulcanized rubbers kept many industries in business, yet chemists started looking for elastomers with more versatility—something able to handle industrial wear and consumer demands alike. Companies like Shell cracked the code with new block copolymers, finding a sweet spot between elasticity and resilience. Their work on styrene-butadiene-styrene (SBS) not only made better tires and adhesives possible, it also opened doors for expanding the range of polymer applications. From my conversations with chemical engineers, SBS changed the landscape because people could assemble them into tough yet flexible plastics that that could bend and bounce back over countless cycles, a huge leap from older brittle materials.

Product Overview

Styrene-Butadiene-Styrene block copolymer stands out in the family of thermoplastic elastomers for its unique three-part structure. SBS links hard styrene blocks on each end to a soft butadiene segment in the middle, producing a material that behaves like rubber but can be processed like plastic. Compared to pure rubber, SBS melts cleanly in extruders and injection molding machines, which lets manufacturers run faster and reduce waste. Asphalt roads and waterproof membranes, which face all kinds of weather, become more durable when SBS gets added in. Walk through a shoe store, and plenty of soles owe their cushioning to SBS. It's one of those “behind-the-scenes” materials; people hardly notice it, yet their day flows smoother because of it. With each kilogram of finished product, companies meet performance criteria that used to require several different ingredients, all mixed together at great expense.

Physical & Chemical Properties

SBS does not grab headlines for flashy scientific properties, but its balance of flexibility, strength, and chemical resistance draws attention from anyone hunting for hard-working materials. The polymer stretches under moderate load, returns to shape, and holds up to oils and many solvents that chew up other plastics or rubbers. People using SBS in shoe factories say it takes dye well, resists cracking from repeated bending, and keeps tackiness low for cleaner assembly. On paper, SBS offers a Shore A hardness roughly between 50 and 90, with elongation at break up to 800%. Its glass transition temperature for the butadiene block sits well below freezing, which means the product remains flexible outdoors or in freezer facilities. The micro-phase separation that forms during cooling results in a mix of rubbery domains and plastic-like regions, giving end products bounce along with some stiffness for support.

Technical Specifications & Labeling

Factories that buy SBS receive bags or drums covered in specifications—melt flow index, tensile strength, styrene content, and more. In my experience touring plants in Asia and Europe, I see different grades labeled with codes like SIS or SBS-30, precise to the composition ratio and viscosity suited for everything from shoe soles to plastic modifiers or sealant compounds. Regulatory compliance appears in the labeling too, minding everything from food contact safety to REACH chemical registration in Europe. Companies print batch numbers and recommended storage temperatures, emphasizing not just performance, but traceability and product reliability. Lab staff often test each batch for gel content and color to keep batch-to-batch consistency high—a non-negotiable requirement when customers run production lines twenty-four hours a day.

Preparation Method

Polymerizing SBS calls for a living anionic process, with careful control of temperature and feed rates. Chemists dissolve styrene and butadiene monomers in hydrocarbon solvents, add catalysts like butyl lithium, and let the reaction run inside special reactors. By controlling the sequence—styrene first, butadiene second, then more styrene—companies end up with ABC block copolymers that can be fine-tuned for hardness and elasticity. After polymerization, excess solvent gets stripped off, and the SBS is either pelletized or made into powder for easier transport. Unlike random copolymers, this process means people can lock down the polymer’s structure every time. I’ve spoken to technicians who stress the importance of reactor cleanliness and precise metering; even a small contaminant or off-ratio charge leads to useless gunk that must be discarded, costing thousands in lost production.

Chemical Reactions & Modifications

Post-polymerization tweaking has led to modified SBS grades with improved performance. Manufacturers sometimes hydrogenate the butadiene segment, which boosts resistance to ozone, ultraviolet light, and heat aging—qualities needed by automotive or roofing products. Sulfonation is another approach, allowing the polymer to better adhere to different surfaces or mix with polar materials. Some researchers add functional groups to improve paint or ink compatibility. Every new modification changes at least one property, so labs spend months running accelerated aging and tensile strength tests before rolling out changes to the factory floor. Hearing from chemists in research centers, successful tweaks come down to collaboration—not just in-house, but between customers and suppliers, since one application’s “improvement” could ruin another’s core benefit.

Synonyms & Product Names

Global suppliers market SBS under various trade names, including Kraton, Cariflex, and Vector, depending on the region or company. SIS (Styrene-Isoprene-Styrene) sometimes appears as a related product, but SBS retains its own following. Industry shorthand sticks: SBS 4302, SBS 4455—numbers often encode info about molecular weight or styrene percentage. In the regulatory arena, SDS documents list synonyms such as Block Copolymer, Thermoplastic Elastomer, or, in some pricing schedules, simply “Rubber Modified Plastic.” The endless list of names can confuse buyers, but experienced procurement staff learn to read between the lines, often favoring specific suppliers based on application history, not just price or label.

Safety & Operational Standards

Workers handling SBS typically deal with low-hazard material; the biggest risks come from the dust created during pelletization, which can irritate lungs and eyes. Factories set up local exhaust to catch stray particles, and keep fire extinguishers close by due to the material’s combustible nature. Globally, the push for better workplace safety means personal protective equipment (PPE)—gloves, masks, goggles—is standard, especially during equipment cleaning or maintenance. I have heard maintenance leads report rare but memorable issues with clogged feeder lines or static buildup, which gets solved with improved housekeeping or anti-static additives in storage bins. For end-users, SBS carries low toxicity under normal use, but careful labeling and regular reviews of safety data keep complaints to a minimum and satisfy insurers.

Application Area

Industries seem to find fresh uses for SBS every year. Roads built with polymer-modified asphalt last longer, shrugging off potholes caused by freeze-thaw cycles and heavy trucks. Footwear plants get creative with bright colors and complex tread patterns, counting on SBS to keep soles soft but strong. In bookbinding, the copolymer holds pages together—no brittle cracking after years on a shelf. Adhesive makers blend SBS into hot-melt systems, giving packaging tape or hygiene products stretch and tack that sticks but peels away without residue. Medical device manufacturers favor the polymer for tubing and film that touches skin, owing to its flexibility and chemical resistance. With every new project, engineers and designers find that SBS lets them do more with less—less raw material, less waste, and fewer additives.

Research & Development

The pressure to improve SBS has not slowed since its invention. Research groups investigate next-generation catalysts for “greener” production, aiming to use less solvent or produce less waste. Biobased versions of the monomers look promising—renewable styrene and butadiene from plant feedstocks could reshape the supply chain and reduce environmental footprint. Labs focus on reinforcing SBS blends with nanoparticles like silica, hoping for stiffer, longer-lasting materials that keep processing ease. Others pursue blends with recycled plastics, answering environmental concerns tied to plastic waste. In trade journals, studies detail how controlling the block length or microstructure tweaks heat resistance and wear properties, sometimes opening doors to entirely new markets.

Toxicity Research

Toxicological studies rate SBS as one of the safer industrial polymers, with minimal risk from skin contact or inhalation during normal handling. Organic vapor exposure remains an issue during production due to solvent use, pushing plants to invest in air quality systems and regular health checks. Chronic exposure to raw monomers like butadiene or styrene, though, poses a different risk profile; regulatory agencies continue to monitor occupational exposure and set strict workplace limits. In consumer goods, product safety reviews confirm that once polymerized, the finished SBS does not leach harmful substances at levels that threaten users. The growth in recycling and reprocessing adds a new angle for research—what degradation products form and under what conditions, and whether recycled SBS impacts human or environmental health. The scientific consensus, so far, gives SBS good marks, provided regulations and best practices are taken seriously.

Future Prospects

Looking ahead, SBS shows strong staying power in both mature and emerging markets. Urbanization drives up demand for stronger, quieter roads, where polymer-modified asphalt offers a clear advantage. Sustainability trends steer research toward bio-based and fully recyclable elastomers, challenging producers to cut fossil fuel inputs. In advanced manufacturing, new techniques like 3D printing are testing SBS-based formulations that flex and recover in ways traditional plastics just can’t manage. Smart packaging and wearable technology, which require stretch, toughness, and skin-friendliness, seem tailor-made for SBS. As a writer and observer, I hear a common refrain: industries keep returning to SBS because it delivers, adapts, and rarely disappoints. The next phase—making it greener and even more robust—comes down to collaboration at every level, from lab benches to factory lines to policy tables, each learning from past success and today’s mistakes.



What is Styrene-Butadiene-Styrene (SBS) block copolymer used for?

What Makes SBS Special?

Walking around on a city street or working with home improvement projects, most folks have run across the tough, flexible material known as styrene-butadiene-styrene, or SBS. This rubbery block copolymer shows up just about everywhere, from shoes to highways. I still remember pulling up asphalt tiles as a kid, smelling that distinct scent, and later learning that this “rubber” comes in large part from the magic of SBS.

Why Do Manufacturers Like SBS?

One of the main reasons for its popularity lies in the simple fact that SBS bends without breaking, stretches, and still snaps back. Manufacturers take this and run with it. Sneakers, tool handles, car mats, and even some smartphone cases owe their soft “grippy” feel to SBS. Because it stands up to traffic and UV rays, road builders spread SBS-modified asphalt on busy streets to fill cracks and keep roads smoother for longer. That keeps maintenance budgets in check, especially for public works folks.

How SBS Boosts Asphalt Performance

Adding SBS to bitumen turns regular old asphalt into something far tougher. Highways and airport runways see a lot of heavy trucks, freeze-thaw cycles, and pounding rain. SBS keeps the pavement from getting brittle, reducing potholes and ruts that irritate drivers and jack up repair costs. Research shows roadways modified with SBS last up to 50% longer compared to unmodified blacktop. Some European and North American cities have made SBS asphalt nearly standard for their main streets because of this durability.

Everyday Uses Around the Home and Office

Flip-flops and waterproof boots owe much of their comfort and grip to SBS blended with other rubber. Even household caulking and seals use it, since the material doesn’t shrink much and shrugs off exposure to water. Adhesives and tapes, especially ones that need to stay sticky in both hot and cold, benefit from the same flexible backbone. Roofing shingles tap into SBS for toughness during summer heat and winter freezes, giving homeowners extra years before needing repairs.

Environmental Questions and Possible Solutions

Folks often ask, what happens to all this SBS after its useful life ends? Unlike pure rubber, SBS does not easily break down in the environment. Piles of worn tires or torn-up roads remind us that materials engineered for resilience might stick around much longer than we want. Some recycling programs grind up old SBS-based products for reuse in construction or paving. Research groups keep looking for ways to improve its recyclability or create bio-based alternatives.

Balancing Benefits and Challenges Ahead

The grip, strength, and weather resistance that SBS provides have changed construction and product design in countless ways. For every smooth highway or comfy shoe, there’s a story about better living through chemistry. Responsible management—finding better recycling, phasing in greener raw materials, and running health studies—are crucial steps so the material continues to serve people well. Companies and researchers working together can maximize benefits without leaving future generations to deal with the mess.

What are the key properties of SBS block copolymer?

Why SBS Matters in Everyday Life

SBS, or styrene-butadiene-styrene, touches a lot of lives in ways most people overlook. Years ago, I worked on a road construction site, and the foreman explained how the flexibility in the pavement helps it last longer. It took me a while to realize he was talking about this very material. SBS gives regular asphalt and plastics a flexibility and toughness you notice once you look for it. Shoes with bouncy soles, packaging that bends but doesn’t snap, and even the pavement underfoot all benefit from SBS.

Strength That Stays Flexible

People often imagine plastics as stiff and unyielding, but SBS changes that expectation. The magic lies in its structure. It’s built like a sandwich, with hard and soft layers — the hard styrene blocks keep things strong, and the rubbery butadiene keeps everything stretchy. This set-up makes SBS much better at handling repeated movement and stress. I once tried to tear an SBS sample with my hands and found it snapped back instead of tearing apart. This property protects products from cracking after months or years of bending.

Temperature Resilience Where It Counts

Hot summers and freezing winters both punish materials. One summer, I saw a stretch of poorly made road buckle in the heat, creating a real hazard. SBS asphalt pavements stood up better under the same conditions. SBS copolymer can stay flexible in the cold, resisting the kind of brittle damage that ruins regular rubber. In high temperatures, it keeps its shape and doesn’t melt or sag. This property makes SBS a good choice for everything from shoe soles to car parts that deal with a range of temperatures every day.

Stickiness That Helps Things Hold Together

Sticky is often seen as a bad thing, but SBS’s tackiness is exactly what helps adhesives work better. Tape manufacturers love SBS because it helps their products grip hard surfaces without drying out. Anyone who has struggled to get old stickers off their bumper has likely encountered the stubborn grip of SBS-based adhesive. The balance of stick and stretch in SBS adhesives gets packaging to seal and labels to stay put long after basic glues give up.

Safe and Clean in Contact with People

Children chew on toys, and people touch packaging all day. Material safety becomes more than a technical issue; it’s a health concern. SBS copolymers don’t leach toxic chemicals under typical conditions. For this reason, toy makers, food-packaging companies, and medical device manufacturers turn to SBS when they want something soft but dependable. The FDA has listed SBS as a food-contact safe material when processed properly, which supports consumer trust in everyday products.

Simple Manufacturing, Serious Results

In the factory, SBS block copolymer mixes easily with other plastics and additives. This quality lets companies fine-tune products for different needs, from soft handles to tough tire treads. My neighbor used to run a small workshop making custom rubber grips for hand tools, and SBS let him create just the right balance of toughness and softness.

Looking Forward

SBS helps real people get better shoes, safer roads, stronger packaging, and cleaner toys — without forcing makers to pick between strength and flexibility. Manufacturers can keep recycling it, making it a practical choice as the world looks for greener solutions. With careful processing and smart engineering, SBS keeps showing up where reliability and comfort matter most.

Is SBS block copolymer safe for food contact or medical use?

Rethinking Plastic in Contact With What We Eat and Heal With

Anyone taking a stroll through the toy aisle or examining certain squeezable food bottles has likely handled SBS, also called styrene-butadiene-styrene block copolymer. Restaurants and hospitals might look at this substance for utensils, packaging, or even medical tubing. People want stuff that's flexible, low-odor, and easy to handle. Those are boxes SBS ticks. Still, food and health need more than convenience.

What Sets Off the Alarm Bells?

The main ingredients in SBS raise eyebrows. Styrene stands linked to some troubling findings. Butadiene doesn’t score high marks for health either. In raw, unfinished form, both sit on watchlists for potential cancer risk. The rubbery magic of SBS comes from chemicals locked together to make a stable structure, and after that magic trick, much of the hazardous stuff drops down to levels too low to cause issues. The question for anyone in the food or medical supply chain is: does that drop go far enough?

Safety Starts With Regulation

For food use, the US FDA and its counterpart in Europe, EFSA, spell out what’s tolerated. They keep eyes on both the base polymer and anything potentially left from making it. In the US market, FDA’s code (21 CFR 177.1810) lists SBS among plastics cleared for some contact with food, based on heavy testing—think migration studies, not just quick looks. The FDA put limits on components like residual styrene monomer to keep migration into food almost negligible.

Medical gear faces different scrutiny. Hospitals hold higher expectations, knowing patients already have enough on their plates. The USP Class VI test stands as the gold standard for plastics used near human tissue and blood. Makers of IV tubing and bags have pushed SBS blends through these hoops, sometimes passing. That doesn’t mean every SBS part is a green light—formulation, additives, and the manufacturing process all play huge roles. If it touches a wound or sits inside the body, SBS usually loses out to options like silicones or more specialized medical-grade rubbers.

Real World, Real Hiccups

One issue often ignored is what happens at the edges. Old or poorly made SBS plastics don’t last forever. With heat, contact with alcohol, or time, they can sometimes break down. That breakdown could let out styrene or other chemicals. Scientific studies share some relief: migration rates stay low under normal temperatures and use levels, especially compared to other plastics. Still, “low” is not “none.” For food packagers, reassurance only goes so far before regulators or major retailers ask their own tougher questions.

Looking for Peace of Mind

If your job involves choosing plastics for something that feeds or treats people, it pays to dig beyond data sheets. Ask for migration testing—real tests, not just computer predictions. Ask about supplier quality and exact recipes. If possible, source from manufacturers with a track record in regulated markets. Watch for updated guidance from FDA, EFSA, or local agencies. Plastics change as science marches forward; safer blends show up, as do new worries. At the end of the day, trust but verify. SBS can serve food or healthcare if kept within watched boundaries, but no shortcut replaces honest scrutiny and up-to-date science.

How should SBS block copolymer be stored and handled?

Storing SBS Block Copolymer Safely

SBS block copolymer lands in warehouses and factories across industries, from shoe factories to asphalt plants. Its value stems from its ability to bend, stretch, and return to shape—which makes what happens in storage rooms important not just for dollars, but also for finished product quality. Bags or bulk containers of SBS don’t just sit in dark corners. They interact with heat, moisture, and even the air. Keep them away from direct sunlight and sources of heat, like steam pipes. Store them somewhere dry, since humidity has a way of creeping in and affecting the polymer’s quality over time.

Importance of Ventilation and Clutter-Free Storage

Stacks of polymer stored on factory floors will sometimes brush up against solvents, lubricants, or other polymers. If bags break, spilled granules can mix with dust or oil—which can change the way compounding or extrusion behaves later on. I learned early that a ventilated storage space saves time and trouble, especially in humid months. Proper air movement helps avoid caking or surface stickiness. Keeping storage areas clean cuts down on cross-contamination and safety risks, like slipping. If the polymer sits alongside chemicals, add clear labels and keep flammables apart. This isn’t just about ticking off safety boxes; it avoids costly mistakes and keeps everybody working confidently.

Dealing with Temperature Changes

I’ve handled SBS in both frozen winters and hot summers. One issue that crops up involves temperature swings. Cold makes the material brittle, so it’s best to keep storage temps stable—think 10°C–35°C as a workable range. Hot storage rooms invite softening, which can gum up handling processes or alter physical properties. Extra heat over long stretches of time can degrade the polymer and sap performance in the field. Controlled environments pay off by keeping material close to the way it arrived from the supplier. That means brisk throughput, fewer rejects, and less firefighting for the crew.

Protecting Against Contamination

Even simple contact with dirt, dust, or loose fibers can change how SBS processes later on—especially in high-precision jobs. Sometimes, I’ve seen how missed details in handling resulted in pumps clogging or mixes failing to hit spec. Store SBS up off concrete floors, on pallets, away from walls that might sweat or shed paint. Make sure bags get used in a first-in, first-out order. This helps keep older stock from degrading at the bottom of a pile, where it’s easy to forget. If something spills, clean up fast and bag the material if it’s still reusable. If not, toss it, since contamination will only get worse over time.

Personal Safety Counts Every Day

SBS brings a low toxicity profile compared to many other industrial chemicals, but it’s no excuse to skip gloves or the dust mask. Even small amounts of dust can irritate airways or skin, especially in high-throughput operations. Place a spill kit within arm’s reach of storage and transfer points. Equip employees with gloves and goggles, and train them to recognize signs of unsafe exposure. Encourage everyone on the floor to speak up if they see poor storage, since it only takes one corner cut to disrupt the workflow—or worse, cause injury.

Final Thoughts on Smart Handling

Safe, tidy, and well-thought-out storage and handling make a difference, both for quality and for the safety of everyone in the building. Small habits—like regular checks on storage areas and keeping containers sealed—add up over weeks and months. As SBS copolymer touches so many products, from tires to toys, knowing how to handle it not only protects your bottom line but also helps build a reputation for doing things right.

How does SBS block copolymer compare to other elastomers like SEBS or natural rubber?

What Sets SBS Apart

SBS, or styrene-butadiene-styrene block copolymer, shows its strength in products that need flexibility and grip at an affordable price. Take shoe soles, for example. Manufacturers count on SBS to create outsoles that take a beating but don't fall apart. Road paving, tool grips, and handle wraps often feature SBS because it bonds well and sticks to fillers and oils. That lowers costs and lets factories churn out plenty of products for daily use.

Looking at SEBS: The Modern Alternative

SEBS stands out as an upgraded cousin. Factories run into problems when products need to last outside, especially in sunlight and heat. SBS cracks or yellows under UV because of its butadiene segments, so you end up with brittle, flaky parts. SEBS solves this by replacing butadiene with ethylene-butylene. The result? Soft plastics that feel like rubber, shrug off weather, and avoid yellowing. Kids’ toys, stroller handles, and garden tools all pick SEBS for this reason.

During my years consulting for consumer goods companies, complaints rolled in about toy grips hardening after a summer in the yard. Early samples relied on SBS. Once the switch flipped to SEBS, the returns dropped off. SEBS's resistance to ozone and sunlight proved itself by surviving backyard abuse all season.

Natural Rubber: Tradition Meets Performance

Natural rubber feels different under the fingers. It stretches far, snaps back, and doesn't quit easily. Car tires, medical gloves, and shock mounts still rely on it, not just out of nostalgia but because nothing quite matches its blend of strength and tack. Tapping latex from trees may sound old-fashioned, but it remains the backbone of essentials like airplane tires, which demand resilience and sheer toughness under wild conditions.

But life gets complicated. Natural rubber costs more and tends to lose its edge in oil, chemicals, or extreme heat. Supply swings, droughts, and disease outbreaks hit global output hard. Companies switching to SBS or SEBS can dodge these problems, cutting cost and shifting to more predictable materials.

Making Judgments in the Real World

A good engineer picks based on what the user faces every day. SBS saves money, holds color dyes well, and takes on a flexible, tacky feel perfect for areas shielded from harsh sunlight. SEBS, in my experience, wins for products left outdoors or subjected to wild temperature swings. It stretches farther and still feels soft after years in the sun. Natural rubber still wins for grip and physical strength where performance trumps price, especially where buyers expect decades of service life.

Today's world leans toward synthetic elastomers because they handle mass production, cut costs, and ease supply worries. SBS and SEBS processing doesn't need tropical plantations or imported materials. The right fit boils down to the end use: choose SBS when cheap flexibility matters, trust SEBS where weather hammers the product, and return to natural rubber only when nothing else stretches and springs back with the same old-school reliability.

Moving Toward Smarter Choices

Better elastomers mean less waste, longer use, and happier customers. Technical teams investing in new compounds look at data on weathering, chemical attack, and cost per use. Real testing, not just literature, uncovers hidden flaws—so lab and field both keep the industry honest. At the end of the day, matching polymer to the job takes experience, plenty of testing, and an eye for the conditions each product will face in the hands of real people.

Styrene-Butadiene-Styrene Block Copolymer
Styrene-Butadiene-Styrene Block Copolymer
Names
Preferred IUPAC name poly(1-phenylethene-block-buta-1,3-diene-block-1-phenylethene)
Other names SBS
Styrene-butadiene-styrene copolymer
SBS rubber
Thermoplastic elastomer SBS
Polystyrene-butadiene block copolymer
Pronunciation /staɪˈriːn bjuːˈtæd.iːn staɪˈriːn blɒk ˈkəʊ.pɒl.ɪ.mər/
Identifiers
CAS Number 9003-55-8
Beilstein Reference 1900225
ChEBI CHEBI:53597
ChEMBL CHEMBL1908881
ChemSpider 15320862
ECHA InfoCard 03e7c4c3-6d10-41f4-873c-576d958bb6e4
EC Number 9003-55-8
Gmelin Reference 1433846
KEGG C21100
MeSH D000072802
PubChem CID 24866246
RTECS number WL6475000
UNII DQ2G6T1NV6
UN number UN2000
CompTox Dashboard (EPA) DTXSID3024986
Properties
Chemical formula (C8H8)x-(C4H6)y-(C8H8)x
Molar mass Molar mass varies; SBS is a polymer with an average molar mass typically ranging from 50,000 to 300,000 g/mol depending on grade.
Appearance White or light yellow porous particle or powder
Odor Slight hydrocarbon odor
Density 0.94 g/cm³
Solubility in water Insoluble
Vapor pressure Negligible
Magnetic susceptibility (χ) -11.2×10⁻⁶ cm³/mol
Refractive index (nD) 1.52
Viscosity Viscosity: 200 - 400 mPa·s (at 25°C, 25% in toluene)
Dipole moment 0.12 D
Thermochemistry
Std molar entropy (S⦵298) 339.1 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) Std enthalpy of formation (ΔfH⦵298) of Styrene-Butadiene-Styrene Block Copolymer is -45.4 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -3595 kJ/mol
Pharmacology
ATC code No ATC code
Hazards
Main hazards No significant hazards.
GHS labelling GHS07
Pictograms GHS07
Signal word Warning
Hazard statements H315, H319, H335
Precautionary statements P210, P261, P280, P304+P340, P305+P351+P338, P312
NFPA 704 (fire diamond) 2-2-0
Flash point > 343°C (649°F)
Autoignition temperature 490°C
LD50 (median dose) >5000 mg/kg (rat, oral)
NIOSH 1007147
PEL (Permissible) PEL (Permissible Exposure Limit) for Styrene-Butadiene-Styrene Block Copolymer: "Not established
REL (Recommended) 5 mg/m3
Related compounds
Related compounds Polystyrene
Polybutadiene
Styrene-Butadiene Rubber (SBR)
Styrene-Isoprene-Styrene (SIS) Block Copolymer
Ethylene-Propylene-Diene Monomer (EPDM)
Acrylonitrile Butadiene Styrene (ABS)
Hydrogenated Styrene-Butadiene-Styrene (SEBS)